Chemical abundances derived using emission-line spectra in ionized gaseous nebulae are between the most useful properties that can be derived to understand the evolution of galaxies from the local Universe up to very high redshifts. Since nitrogen is one of the most abundant metals in the gas-phase of galaxies and its emission-lines can be measured many times instead of those emitted by oxygen, it is important to be aware of the implications of the variations in the nitrogen-to-oxygen ratio for the derivation of total metallicity and what are the advantages of using this abundance ratio to derive other evolutionary properties in different emission-line objects. We will also see the utility of some observational techniques, such integral field spectroscopy, to disentangle between different processes implied in the excess of observed nitrogen as derived from integrated observations.