Using deep photometry SBFs have been traditionally used to determine galaxy distances. We have recentlycomputed SBF spectra of stellar populations at moderately high resolution,which are fully based on empirical stellar spectral libraries. We show that the SBF spectraprovide new means to perform the stellar population studies, which, so far, have been tackled on the basis of the mean properties. We find that theSBFs are able to unveil very metal-poor components at the one percent level, which are not possible to disentangle with the standard analysis. In massive Early-Type Galaxies suchmetal-poor components correspond to the first stages in their chemicalenrichment and, therefore, the SBFs provide stringent constrains on their formation.